How much of the recent CO2 increase is due to human activities?

Contributed by Corinne Le Quéré, University of East Anglia.

This question keeps coming back, although we know the answer very well: all of the recent CO2 increase in the atmosphere is due to human activities, in spite of the fact that both the oceans and the land biosphere respond to global warming. There is a lot of evidence to support this statement which has been explained in a previous posting here and in a letter in Physics Today . However, the most convincing arguments for scientists (based on isotopes and oxygen decreases in the atmosphere) may be hard to understand for the general public because they require a high level of scientific knowledge. I present simpler evidence of the same statement based on ocean observations, and I explain how we know that not only part of the atmospheric CO2 increase is due to human activities, but all of it.

On time-scales of ~100 years, there are only two reservoirs that can naturally exchange large quantities of CO2 with the atmosphere: the oceans and the land biosphere (forests and soils). The mass of carbon (carbon is the “C” in CO2) must be conserved. If the atmospheric CO2 increase was caused, even in part, by carbon emitted from the oceans or the land, we would measure a carbon decrease in these two reservoirs.

Number of observations of carbon decreasing in the global oceans: zero.

Number of observations of carbon increasing in the global oceans: more than 20 published studies using 6 independent methods.

The methods are:

(1) direct observations of the partial pressure of CO2 at the ocean surface (Takahashi et al. 2002),

(2) observations of the spatial distribution of atmospheric CO2 which show how much carbon goes in and out of the different oceanic regions (Bousquet et al. 2000),

(3) observations of carbon, oxygen, nutrients and CFCs combined to remove the mean imprint of biological processes (Sabine et al. 2004),

(4) observations of carbon and alkalinity for two time-periods combined with an estimate of water age based on CFCs (McNeil et al. 2002), and the simultaneous observations of atmospheric CO2 increase and the decrease in (5) oxygen (Keeling et al. 1996), and (6) carbon 13 (Ciais et al. 1995) in the atmosphere.

The principle of the last two methods is that both fossil fuel burning and biospheric respiration consume oxygen and reduce carbon 13 as they produce CO2, but the exchange of CO2 with the oceans has only a small impact on atmospheric oxygen and carbon 13. The measure of atmospheric CO2 increase together with oxygen or carbon 13 decrease gives the distribution between the different reservoirs.

All the estimates show that the carbon content of the oceans is increasing by ~ 2±1 PgC every year (current burning of fossil fuel is ~7 PgC per year). One method is able to go back in time and shows that the carbon content of the oceans has increased by 118±19 PgC in the last 200 years. There is some uncertainty about the exact amount that the oceans have taken up, but not about the direction of the change. The oceans cannot be a source of carbon to the atmosphere, because we observe them to be a sink of carbon from the atmosphere.

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