Beck to the future

Guest commentary from Georg Hoffmann

Our understanding of the natural carbon cycle has greatly improved since the times of Svante Arrhenius (1859-1927) and Guy Stewart Callendar (1898-1964). We know what the atmospheric background value of CO2 currently is (it passed 380ppm last year, about 100ppm over the pre-industrial level), we know the seasonal/diurnal cycle in different environments, we have been able to put reasonable constraints on terrestrial and marine sources and sinks, and finally we know the impact of fuel combustion both globally and locally in heavily polluted areas.

The most impressive record documenting the human role in atmospheric CO2 concentrations was recently published in the AR4 SPM showing the comparably minor variations of CO2 during the Holocene (as measured in various ice cores) followed by the abrupt increase of greenhouse gases (GHGs) since the start of industrialisation in the 19th century (figure).

It took a lot of long and painful lessons for scientists to come to this level of understanding of the natural carbon cycle and its anthropogenic contributions. Difficulties arose mainly from two problems: First, sampling of air masses and subsequent measuring of CO2 concentrations was in itself a difficult problem. Measuring techniques were based on titration with limewater or baryta (the Pettenkofer process) and needed a significant amount of technical skill and patience for a proper measurement. The regular use of a CO2 standard to permanently check the measurement quality was something of an exception.

Secondly, nearly all early sampling facilities were tested in continental environments often under the sporadic influence of heavily polluted air masses (such as Paris, Parc Montsouris, Copenhagen, Dieppe etc.). How large is the influence of such “CO2 pollution”? A quick tour through my car-traffic-saturated home town, Paris, can give us a good first impression:

  • Jardin Luxembourg (major but still tiny green spot in the center of Paris) 425ppm
  • Place de la Bastille: 430ppm
  • Place de l’Etoile (the crazy huge roundabout around the Arc de Triomphe): 508ppm
  • And the winner was Place de la Nation: 542ppm (ie 160ppm over background!).

All these measurements by David Widory and Marc Javoy (reference below) were snapshot measurements, but they show how CO2 concentrations can vary strongly due to nearby fossil fuel combustion. Even in apparently “natural” environments there are many technical pitfalls to avoid. Strong CO2 fluxes due to the breathing (i.e. photosynthesis and respiration) of the biosphere are producing large diurnal cycles. A sampling site too close to the surface or shielded by a surrounding forest can easily bias the CO2 signal by several dozens of ppm.

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