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Greenhouse gases

Calculating the greenhouse effect

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In another forum (on a planet far, far away), the following quote recently came up:

….the combined effect of these greenhouse gases is to warm Earth’s atmosphere by about 33 ºC, from a chilly -18 ºC in their absence to a pleasant +15 ºC in their presence. 95% (31.35 ºC) of this warming is produced by water vapour, which is far and away the most important greenhouse gas. The other trace gases contribute 5% (1.65 ºC) of the greenhouse warming, amongst which carbon dioxide corresponds to 3.65% (1.19 ºC). The human-caused contribution corresponds to about 3% of the total carbon dioxide in the present atmosphere, the great majority of which is derived from natural sources. Therefore, the probable effect of human-injected carbon dioxide is a miniscule 0.12% of the greenhouse warming, that is a temperature rise of 0.036 ºC. Put another way, 99.88% of the greenhouse effect has nothing to do with carbon dioxide emissions from human activity8.

We’ve discussed the magnitude of the greenhouse effect before, but it might be helpful to step through this ‘back-of-the-agenda’ calculation and see what the numbers really give. (Deltoid has also had a go at some of these mis-statements). [Read more…] about Calculating the greenhouse effect

Scientists baffled!

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Translations: (Français) (English)

Every so often a scientific paper comes out that truly surprises. The results of Keppler et al in Nature this week is clearly one of those. They showed that a heretofore unrecognised process causes living plant material to emit methane (CH4, the second most important trace greenhouse gas), in quantities that appear to be very significant globally. This is surprising in two ways – firstly, CH4 emission is normally associated with anaerobic (oxygen-limited) environments (like swamps or landfills) but chemistry in plants is generally thought of as ‘aerobic’ i.e. not oxygen-limited, and secondly, because although the total budget for methane has some significant uncertainty associated with it (see the IPCC assessment here), the initial estimates of this effect (between 62–236 Tg/yr out of a total source of 500+ Tg/yr!) give numbers that might be difficult to incorporate without some significant re-evaluations elsewhere.

Reactions so far have been guarded, and there will undoubtedly be a scramble to check and refine the estimates of this process’s importance. Once the dust settles though, the situation may not be so different to before – some emissions may turn out to have been mis-identified, this source may not be as large as these initial estimates (10-30% of total sources) suggest, or it might radically challenge our current understanding of methane’s sources and sinks. However, the process by which this is decided will demonstrate clearly that the scientific method is alive and well in the climate sciences. That is, as long as a work is careful and the conclusions sound, papers that upset the apple cart can appear in the major journals and have a good chance of ending up being accepted by the rest of the field (providing the conclusions hold up of course!).

Update 19 Jan: The authors of the study have released a clarification of their study to counter some of the misleading conclusions that had appeared in the press.

Polar Amplification

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Guest commentary by Cecilia Bitz, University of Washington

“Polar amplification” usually refers to greater climate change near the pole compared to the rest of the hemisphere or globe in response to a change in global climate forcing, such as the concentration of greenhouse gases (GHGs) or solar output (see e.g. Moritz et al 2002). Polar amplification is thought to result primarily from positive feedbacks from the retreat of ice and snow. There are a host of other lesser reasons that are associated with the atmospheric temperature profile at the poles, temperature dependence of global feedbacks, moisture transport, etc. Observations and models indicate that the equilibrium temperature change poleward of 70N or 70S can be a factor of two or more greater than the global average. [Read more…] about Polar Amplification

Naturally trendy?

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From time to time, there is discussion about whether the recent warming trend is due just to chance. We have heard arguments that so-called ‘random walk‘ can produce similar hikes in temperature (any reason why the global mean temperature should behave like the displacement of a molecule in Brownian motion?). The latest in this category of discussions was provided by Cohn and Lins (2005), who in essence pitch statistics against physics. They observe that tests for trends are sensitive to the expectations, or the choice of the null-hypothesis .

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Natural Variability and Climate Sensitivity

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One of the central tasks of climate science is to predict the sensitivity of climate to changes in carbon dioxide concentration. The answer determines in large measure how serious the consequences of global warming will be. One common measure of climate sensitivity is the amount by which global mean surface temperature would change once the system has settled into a new equilibrium following a doubling of the pre-industrial CO2 concentration. A vast array of thought has been brought to bear on this problem, beginning with Arrhenius’ simple energy balance calculation, continuing through Manabe’s one-dimensional radiative-convective models in the 1960’s, and culminating in today’s comprehensive atmosphere-ocean general circulation models. The current crop of models studied by the IPCC range from an equilibrium sensitivity of about 1.5°C at the low end to about 5°C at the high end. Differences in cloud feedbacks remain the principal source of uncertainty. There is no guarantee that the high end represents the worst case, or that the low end represents the most optimistic case. While there is at present no compelling reason to doubt the models’ handling of water vapor feedback, it is not out of the question that some unanticipated behavior of the hydrological cycle could make the warming somewhat milder — or on the other hand, much, much worse. Thus, the question naturally arises as to whether one can use information from past climates to check which models have the most correct climate sensitivity.

[Read more…] about Natural Variability and Climate Sensitivity

Methane hydrates and global warming

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There is an enormous amount of methane (CH4) on earth frozen into a type of ice called methane hydrate. Hydrates can form with almost any gas and consist of a ‘cage’ of water molecules surrounding the gas. (The term ‘clathrate’ more generally describes solids consisting of gases are trapped within any kind of cage while hydrate is the specific term for when the cage is made of water molecules). There are CO2 hydrates on Mars, while on Earth most of the hydrates are filled with methane. Most of these are in sediments of the ocean, but some are associated with permafrost soils.

Methane hydrates would seem intuitively to be the most precarious of things. Methane hydrate melts if it gets too warm, and it floats in water. Methane is a powerful greenhouse gas, and it degrades to CO2, another greenhouse gas which accumulates in the atmosphere just as fossil fuel CO2 does. And there is a lot of it, possibly more than the traditional fossil fuel deposits. Conceivably, climate changes could affect these deposits. So what do we know of the disaster-movie potential of the methane hydrates?

[Read more…] about Methane hydrates and global warming

Debate over the Early Anthropogenic Hypothesis

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There have been a few mentions of the ‘early anthropocene’ hypothesis recently (cf. the EPICA CO2 results, and Strange Bedfellows). We therefore welcome Bill Ruddiman to RealClimate to present his viewpoint and hopefully stimulate further discussion – gavin.

[Addendum: For a non-technical backgrounder on the ‘early anthropocene’ hypothesis and its significance in the context of anthropogenic climate change, see Bill Ruddiman’s article “How Did Humans First Alter Global Climate?” from the March 2005 issue of “Scientific American” (first two paragraphs available for free; full article must be purchased). -mike]

Guest posting from Bill Ruddiman, University of Virginia

The hypothesis (Ruddiman, 2003) that early agriculture caused large enough emissions of greenhouse gases millennia ago to offset a natural climatic cooling remains controversial. The centerpiece of the hypothesis was a comparison of the increases of CO2 and CH4 values in Vostok ice during the current (Holocene) interglaciation versus the (natural) drops during similar portions of the three previous interglaciations. [Read more…] about Debate over the Early Anthropogenic Hypothesis

Greenhouse gases help seasonal predictions

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Translations: (Français) (English)

The conventional wisdom in meteorology has been that certain factors such as the complete oceanic state and the exact concentrations of greenhouse gases are of minor importance for a normal weather forecast. Moreover, whereas sea surface temperatures (SST) are important, the deep sea temperatures are believed to have little impact for predictions for the next few days. The reason is that the ocean reacts slowly to changes in the atmosphere (has much higher inertia and much higher heat capacity). Hence, the most important information needed for such a weather forecast is the atmospheric initial conditions, a description of what the atmosphere and the SST look like when the weather model starts computing the weather evolution.

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650,000 years of greenhouse gas concentrations

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Translations: (Français) (English)

The latest results from the EPICA core in Antarctica have just been published this week in Science (Siegenthaler et al. and Spahni et al.). This ice core extended the record of Antarctic climate back to maybe 800,000 years, and the first 650,000 years of ice have now been analysed for greenhouse gas concentrations saved in tiny bubbles. The records for CO2, CH4 and N2O both confirm the Vostok records that have been available for a few years now, and extend them over another 4 glacial-interglacial cycles. This is a landmark result and a strong testament to the almost heroic efforts in the field to bring back these samples from over 3km deep in the Antarctica ice. So what do these new data tell us, and where might they lead? [Read more…] about 650,000 years of greenhouse gas concentrations

Busy Week for Water Vapor

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It’s been a busy week for water vapor, and I have two recent papers to discuss. The first is the paper "Anthropogenic greenhouse forcing and strong water vapor feedback increase temperature in Europe" by Rolf Philipona et al. (GRL, 2005, subscription required for full text), which has attracted a certain amount of media attention. The overall goal of the paper is to understand, from a physical standpoint, why European temperatures have been increasing three times faster than the Northern Hemisphere average. It focuses on the changes between 1995 and 2002, over which time good surface radiation budget observations are available. The paper reports some results on the role of large scale circulation changes (which they conclude are minor) but I’ll concentrate on the results relating to water vapor.

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